Donor/acceptor complex of triphenylene and trinitrotoluene on Au(111): a scanning tunneling microscopy study.
نویسندگان
چکیده
The co-adsorption of trinitrotoluene (TNT), a typical π-electron acceptor, and triphenylene (TP), a typical π-electron donor, on a Au(111) surface was investigated by in situ Electrochemical Scanning Tunneling Microscopy (ECSTM). DFT calculations proved that parallelly stacked and well-overlapped TP and TNT molecules can form Donor-Acceptor dyads through intermolecular π-π charge transfer, which agree well with the experimental results in the present work.
منابع مشابه
TNT adsorption on Au(111): electrochemistry and adlayer structure.
Electrochemistry and adlayer structure of trinitrotoluene (TNT) on an Au(111) electrode were investigated using cyclic voltammetry and in situ electrochemical scanning tunneling microscopy (ECSTM).
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ورودعنوان ژورنال:
- Chemical communications
دوره 47 24 شماره
صفحات -
تاریخ انتشار 2011